ORGANIC CHEMISTRY 4524 SPRING 2017

HANDOUTS AND EXERCISES

 

Date issued

title

Mon 23 Jan

Course lecture syllabus

Mon 23 Jan

Course lab syllabus

Mon 23 Jan

Supplement 15 from Fall 2016: Re-summary of reactions of alkenes

Fri 27 Jan

Exercise 1  (take home practice)

 

Exercise 1 answers

(skipped this)

Supplement 0: Brown’s Markovnikoff and Anti-Markovnikoff Routes to Alcohols from Alkenes: the bridgehead pictures (not done)

Mon 30 Jan

Supplement 1: stereochemical language and assignment of 1 chiral center molecules

Fri 3 Feb

Exercise 2: 1 center chiral assignment

 

Exercise 2 answers

Mon 6 Feb

Supplement 2; two center chiral molecules

Mon 6 Feb

Exercise 3: two center chiral molecules

 

Exercise 3:  answers

Wed 8 Feb

Summary List : stereochemistry

Wed 8 Feb, Fri 10 Feb

Exercise 4: naming alkynes

 

Exercise 4:  answers

Monday 13 Feb

Exercise 5: making alkynes

 

Exercise 5: answers

Wednesday 15 Feb

Exercise 6: alkyne reactions

 

Exercise 6: answers

Wed 15 Feb

Exercise 7: roadmap problems with alkynes

 

Exercise 7 answers

Wed 22 Feb

Supplement 3: summary  alkadiene chemistry

Mon 27 Feb

Exercise 8: cycloadditions, carbocation and bridgehead additions on dienes

 

Exercise 8 answers

Wed 1 Mar

Exercise 9: allylic resonance chemistry

 

Exercise 9: answers

Wed 8 March

Exercise 10: counting pi electrons and aromaticity

 

Exercise 10: answers

Wed 8 March

Supplement 4: Electrophilic aromatic substitution reactions on benzene

Fri 10 March

o,m,p director group tables

Fri 10 March and Mon 20 March

Exercise 12: multiple substituent effects for aromatic substitution

 

Exercise 12: answers

Wed 22 March

Exercise 11: Road map problems with aromatics part 1 and electrophilic aromatic heavy hitters

 

Exercise 11: answers

Wed 22 March

Supplement 5: substituted aromatic ring reactions

 

Exercise 12: answers

Mon 27 March

Exercise 13: Roadmap problems with Aromatics

 

Exercise 13: answers

Fri 31 March

Supplement 6: naming aromatics

Fri 31 March

Supplement 7: Routes to and from ROH

Fri 31 March

Supplement 8: Grignard Reactions Reviewed

Mon 10 April

Exercise 14a and 14b: reactions to ROH

 

Exercise 14a, b answers

Wed 12 April

Exercise 15a and 15b: short trips with ROH and an alcohol road map show

 

Exercise 15a and 15b: answers

 

List of Mechanisms and Rules for Mechanism Inquisition

Wed 19 April

Supplement 9: Routes to Aldehydes and Ketones + side note on making acid chlorides

 

Supplement 10: (last one)-New Reactions of Aldehydes and Ketones